Skip to main content

Advertisement

SpringerLink
Log in

Optimization of a photopolymerizable material based on a photocyclic initiating system using holographic recording

  • Paper
  • Published:
Photochemical & Photobiological Sciences Aims and scope Submit manuscript

Abstract

A set of photoinitiating systems (PIS) for free radical photopolymerization was studied using time-resolved spectroscopic experiments, real-time FTIR and holographic recording. It is shown that the efficiency of the photoinitiating system can be drastically increased when a redox additive is added to the conventional dye/coinitiator system by virtue of photocyclic behaviour. The homogeneous photopolymerization process was found to reach a fast vitrification, limiting the conversion at about 55%. By contrast, holographic recording underlines the differences in photoinitiating system reactivity, allowing diffraction efficiencies close to unity for the most reactive PIS.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Notes and references

  1. R. Schwalm, UV Coatings, Basics, Recent Developments and New Applications, Elsevier, Amsterdam, 2007.

    Google Scholar 

  2. X. Allonas, C. Croutxe-Barghorn, J. P. Fouassier, J. Lalevee, J. P. Malval and F. Morlet-Savary, in Lasers in Chemistry. Influencing Matter, ed. M. Lackner, Wiley, Weinheim, 2008, ch. 35, vol.2, p.1001.

    CAS  Google Scholar 

  3. W. Schnabel, Polymers and Light: Fundamentals and Technical Applications, 2007, p.396.

    Book  Google Scholar 

  4. K. Curtis, L. Dhar and W. L. Wilson, Comprehensive Nanoscience and Technology, Elsevier, 2011, vol.4, pp. 615–630.

    Article  Google Scholar 

  5. S. Gallego, A. Márquez, M. Ortuño, S. Marini and J. Francés, Opt. Mater. 2011, 33, 1626–1629.

    Article  CAS  Google Scholar 

  6. SPIE’s Holography Newsletter, Special Issue on: Holographic Materials for Data Storage, 2003, 14(2)

    Google Scholar 

  7. M. M. Wang and S. C. Esener, Appl. Opt. 2000, 39, 1826–1834.

    Article  CAS  PubMed  Google Scholar 

  8. W. J. Joo, C.-H. Oh, S.-H. Song, P.-S. Kim and Y.-K. Han, J. Phys. Chem. B 2001, 105, 8322–8326.

    Article  CAS  Google Scholar 

  9. U.-S. Rhee, H. J. Caulfield, C. S. Vikram and J. Shamir, Appl. Opt. 1995, 34, 846–853.

    Article  CAS  PubMed  Google Scholar 

  10. N. Suzuki, Y. Tomita and T. Kojima, Appl. Phys. Lett. 2002, 81, 4121–4123.

    Article  CAS  Google Scholar 

  11. T. J. Trentler, J. E. Boyd and V. L. Colvin, Chem. Mater. 2000, 12, 1431–1438.

    Article  CAS  Google Scholar 

  12. Y. Takamatsu, D. Dunmeyer, E. L. Thomas and C. Warde, Opt. Lett. 2008, 33, 7–9.

    Article  CAS  PubMed  Google Scholar 

  13. E. Leite, I. Naydenova, S. Mintova, L. Leclercq and V. Toal, Appl. Opt. 2010, 49, 3652–3660.

    Article  CAS  PubMed  Google Scholar 

  14. K. Chikama, K. Mastubara, S. Oyama and Y. Tomita, J. Appl. Phys. 2008, 103, 113108.

    Article  CAS  Google Scholar 

  15. L. Hesselink, S. S. Orlov and M. C. Bashaw, Proc. IEEE 2004, 92, 1231–1280.

    Article  CAS  Google Scholar 

  16. Y. Bi and D. C. Neckers, J. Photochem. Photobiol., A 1993, 74, 221–230.

    Article  CAS  Google Scholar 

  17. D. F. Eaton, Top. Curr. Chem. 1990, 156, 199–225.

    Article  CAS  Google Scholar 

  18. T. Urano, E. Hino, H. Ito, M. Shimizu and T. Yamaoka, Polym. Adv. Technol. 1998, 9, 825–830.

    Article  CAS  Google Scholar 

  19. X. Allonas, J. P. Fouassier, M. Kaji, M. Miyasaka and T. Hidaka, Polymer 2001, 42, 7627–7634.

    Article  CAS  Google Scholar 

  20. A. Ibrahim, C. Ley, O. I. Tarzi, J. P. Fouassier and X. Allonas, J. Photopolym. Sci. Technol. 2010, 23, 101–108.

    Article  CAS  Google Scholar 

  21. O. I. Tarzi, X. Allonas, C. Ley and J. P. Fouassier, J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 2594–2603.

    Article  CAS  Google Scholar 

  22. J. Karolin, L. B. A. Johansson, L. Strandberg and T. Ny, J. Am. Chem. Soc. 1994, 116, 7801–7806.

    Article  CAS  Google Scholar 

  23. F. Li, S. I. Yang, Y. Ciringh, J. Seth, C. H. Martin, D. L. Singh, D. Kim, R. R. Birge, D. F. Bocian, D. Holten and J. S. Lindsey, J. Am. Chem. Soc. 1998, 120, 10001–10017.

    Article  CAS  Google Scholar 

  24. P. Toele, H. Zhang, C. Trieflinger, J. Daub and M. Glasbeek, Chem. Phys. Lett. 2003, 368, 66–75.

    Article  CAS  Google Scholar 

  25. J. Bañuelos Prieto, F. López Arbeloa, V. Martínez Martínez, T. Arbeola López, F. Amat-Guerri, M. Liras and I. López Arbeloa, Chem. Phys. Lett. 2004, 385, 29–35.

    Article  CAS  Google Scholar 

  26. K. Jagtap, D. Maity, A. Ray, K. Dasgupta and S. Ghosh, Pramana 2010, 75, 985–989.

    Article  CAS  Google Scholar 

  27. A. Costela, I. García-Moreno, C. Gomez, R. Sastre, F. Amat-Guerri, M. Liras, F. López Arbeloa, J. Bañuelos Prieto and I. López Arbeloa, J. Phys. Chem. A 2002, 106, 7736–7742.

    Article  CAS  Google Scholar 

  28. S. Suzuki, X. Allonas, J.-P. Fouassier, T. Urano, S. Takahara and T. Yamaoka, J. Photochem. Photobiol., A 2006, 181, 60–66.

    Article  CAS  Google Scholar 

  29. A. A. Gorman, I. Hamblett, T. A. King and M. D. Rahn, J. Photochem. Photobiol., A 2000, 130, 127–132.

    Article  CAS  Google Scholar 

  30. G. Jones, S. Kumar, O. Klueva and D. Pacheco, J. Phys. Chem. A 2003, 107, 8429–8434.

    Article  CAS  Google Scholar 

  31. T. G. Pavlopoulos, J. H. Boyer, M. Shah, K. Thangaraj and M.-L. Soong, Appl. Opt. 1990, 29, 3885–3886.

    Article  CAS  PubMed  Google Scholar 

  32. F. López Arbeloa, T. López Arbeloa, I. López Arbeloa, I. García-Moreno, A. Costela, R. Sastre and F. Amat-Guerri, Chem. Phys. 1998, 236, 331–341.

    Article  Google Scholar 

  33. C. Angel, G.-M. Inmaculada, G. Clara, G. Olga and S. Roberto, Chem. Phys. Lett. 2003, 369, 656–661.

    Article  CAS  Google Scholar 

  34. M. S. Mackey and W. N. Sisk, Dyes Pigm. 2001, 51, 79–85.

    Article  CAS  Google Scholar 

  35. M. Ahmad, T. A. King, D.-K. Ko, B. Heon Cha and J. Lee, Opt. Commun. 2002, 203, 327–334.

    Article  CAS  Google Scholar 

  36. M. D. Rahn, T. A. King, A. A. Gorman and I. Hamblett, Appl. Opt. 1997, 36, 5862–5871.

    Article  CAS  PubMed  Google Scholar 

  37. N. Tanaka and W. N. Sisk, J. Photochem. Photobiol., A 2005, 172, 109–114.

    Article  CAS  Google Scholar 

  38. G. Beer, C. Niederalt, S. Grimme and J. Daub, Angew. Chem., Int. Ed. 2000, 39, 3252–3255.

    Article  CAS  Google Scholar 

  39. K. Rurack, M. Kollmannsberger and J. Daub, Angew. Chem., Int. Ed. 2001, 40, 385–387.

    Article  CAS  Google Scholar 

  40. T. Arbeola López, F. López Arbeloa, I. López Arbeloa, I. García-Moreno, A. Costela, R. Sastre and F. Amat-Guerri, Chem. Phys. Lett. 1999, 299, 315–321.

    Article  Google Scholar 

  41. R. E. Hermes, T. H. Allik, S. Chandra and J. A. Hutchinson, Appl. Phys. Lett. 1993, 63, 877–879.

    Article  CAS  Google Scholar 

  42. T. Urano, E. Ohno-Okumura, K. Sakamoto, H. Ito and T. Yamaoka, J. Photopolym. Sci. Technol. 1999, 12, 747–757.

    Article  CAS  Google Scholar 

  43. M. Kollmannsberger, K. Rurack, U. Resch-Genger and J. R. Daub, J. Phys. Chem. A 1998, 102, 10211–10220.

    Article  CAS  Google Scholar 

  44. F. Bergström, I. Mikhalyov, P. Hägglöf, R. Wortmann, T. Ny and L. B.-A. Johansson, J. Am. Chem. Soc. 2001, 124, 196–204.

    Article  CAS  Google Scholar 

  45. S. Noppakundilograt, S. Suzuki, T. Urano, N. Miyagawa, S. Takahara and T. Yamaoka, Polym. Adv. Technol. 2002, 13, 527–533.

    Article  CAS  Google Scholar 

  46. T. Urano, H. Ito and T. Yamaoka, Polym. Adv. Technol. 1999, 10, 321–328.

    Article  CAS  Google Scholar 

  47. S. Blaya, P. Acebal, L. Carretero and A. Fimia, Opt. Commun. 2003, 228, 55–61.

    Article  CAS  Google Scholar 

  48. M. M. Wang and S. C. Esener, Appl. Opt. 2000, 39, 1826–1834.

    Article  CAS  PubMed  Google Scholar 

  49. M. De Sarkar, J. Qi and G. P. Crawford, Polymer 2002, 43, 7335–7344.

    Article  Google Scholar 

  50. M. D. Schulte, S. J. Clarson, L. V. Natarajan, D. W. Tomlin and T. J. Bunning, Liq. Cryst. 2000, 27, 467–475.

    Article  CAS  Google Scholar 

  51. T. M. Roper, T. Kwee, T. Y. Lee, C. A. Guymon and C. E. Hoyle, Polymer 2004, 45, 2921–2929.

    Article  CAS  Google Scholar 

  52. C. Carre, R. Chevallier, B. Mailhot and A. Rivaton, Basics and Applications of Photopolymerization Reactions, ed. J. P. Fouassier and X. Allonas, Research Signpost, Trivandrum, India, 2010, vol.3, pp. 175–184.

    CAS  Google Scholar 

  53. S. Massenot, R. Chevallier, J.-L. de Bougrenet de la Tocnaye and O. Parriaux, Opt. Commun. 2007, 275, 318–323.

    Article  CAS  Google Scholar 

  54. P. Jacques, D. Burget and X. Allonas, New J. Chem. 1996, 30, 933.

    Google Scholar 

  55. C. Decker and K. Moussa, Macromolecules 1989, 22, 4455–4462.

    Article  CAS  Google Scholar 

  56. X. Allonas, J. P. Fouassier, L. Angiolini and D. Caretti, Helv. Chim. Acta 2001, 84, 2577–2588.

    Article  CAS  Google Scholar 

  57. S. Massenot, J. L. Kaiser, R. Chevallier and Y. Renotte, Appl. Opt. 2004, 43, 5489–5497.

    Article  CAS  PubMed  Google Scholar 

  58. S. Gallego, M. Ortuno, C. Neipp, C. Garcia, A. Beléndez and I. Pascual, Opt. Commun. 2003, 215, 263–269.

    Article  CAS  Google Scholar 

  59. D. Rehm and A. Weller, Isr. J. Chem. 1970, 8, 259.

    Article  CAS  Google Scholar 

  60. C. Decker, Prog. Polym. Sci. 1996, 21, 593–650.

    Article  CAS  Google Scholar 

  61. C. Decker, Macromol. Rapid Commun. 2002, 23, 1067–1093.

    Article  CAS  Google Scholar 

  62. J. R. Lawrence, F. T. O’Neill and J. T. Sheridan, Optik 2001, 112, 449.

    Article  CAS  Google Scholar 

  63. M. R. Gleeson and J. T. Sheridan, J. Opt. A: Pure Appl. Opt. 2009, 11, 024008.

    Article  CAS  Google Scholar 

  64. M. Kveton, A. Havránek, P. Fiala and I. Richter, Polym. Bull. 2007, 58, 253.

    Article  CAS  Google Scholar 

  65. S. Han, M. Lee and B. K. Kim, Opt. Mater. 2011, 34, 131–137.

    Article  CAS  Google Scholar 

  66. H. Kogelnik, Bell Syst. Tech. J. 1969, 48, 2909–2947.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratory of Macromolecular Photochemistry and Engineering, University of Haute Alsace, ENSCMu, 3 rue Alfred Werner, 68093, Mulhouse, France

    A. Ibrahim, C. Ley, X. Allonas & O. I. Tarzi

  2. UEB, Université Européenne de Bretagne, France

    A. Chan Yong & C. Carré

  3. Institut Mines-Télécom, Télécom Bretagne, Optics Department, Technopôle Brest Iroise CS 83818, 29238, Brest Cedex 3, France

    A. Chan Yong

  4. CNRS, UMR 6082 FOTON, Enssat, 6 rue de Kerampont, BP 80518, 22305, Lannion, France

    A. Chan Yong & C. Carré

  5. Institut Mines-Télécom, Mines de Douai, 941 Rue Charles Bourseul, 59508, Douai Cedex, France

    R. Chevallier

Authors
  1. A. Ibrahim
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Ley
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. X. Allonas
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. I. Tarzi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. Chan Yong
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. C. Carré
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. R. Chevallier
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to X. Allonas.

Additional information

This article is published as part of a themed issue in honour of Jean-Pierre Desvergne on the occasion of his 65th birthday.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ibrahim, A., Ley, C., Allonas, X. et al. Optimization of a photopolymerizable material based on a photocyclic initiating system using holographic recording. Photochem Photobiol Sci 11, 1682–1690 (2012). https://doi.org/10.1039/c2pp25099c

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1039/c2pp25099c

Search

Navigation