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2-Chlorophenol photooxidation using immobilized meso-tetraphenylporphyrin in polyurethane nanofabrics

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Abstract

The photosensitized oxidation of 2-chlorophenol (2-CP) in aqueous solution using immobilized meso-tetraphenylporphyrin (TPP) in polyurethane nanofabrics was studied. The influence of various parameters on the reaction efficiency was investigated, i.e., 2-CP concentration, oxygen content and pH of the reaction solution and the stability of immobilized photosensitizer at the multiple use. The resistance of the structure of the photosensitizer carrier toward the solutions of various pH was also studied. The participation of molecular singlet oxygen (1O2) in the photooxidation was tested using NaN3 and imidazole quenchers of 1O2. The kinetics of the process was described using Langmuir-Hinshelwood model.

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Authors and Affiliations

  1. Faculty of Process and Environmental Engineering, Technical University of Lodz, ul. Wólczańska 213, 90-924, Łódź, Poland

    Marta Gmurek & Jacek S. Miller

  2. Faculty of Science, Charles University in Prague, Hlavova 2030, 128 43, Praha 2, Czech Republic

    Jiri Mosinger

  3. Institute of Inorganic Chemistry, v.v.i., Academy of Sciences of the Czech Republic, 250 68, Řež, Czech Republic

    Jiri Mosinger

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  1. Marta Gmurek
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  2. Jiri Mosinger
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  3. Jacek S. Miller
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Correspondence to Marta Gmurek.

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Gmurek, M., Mosinger, J. & Miller, J.S. 2-Chlorophenol photooxidation using immobilized meso-tetraphenylporphyrin in polyurethane nanofabrics. Photochem Photobiol Sci 11, 1422–1427 (2012). https://doi.org/10.1039/c2pp25010a

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