Issue 57, 2012
From the journal:

Chemical Communications

Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(ii) complex†

Michael I. Lipschutza  and  T. Don Tilley*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, Berkeley, USA
E-mail: tdtilley@berkeley.edu

Abstract

A strictly two-coordinate nickel(II) bis(amido) complex has been prepared and its reactivity towards a variety of small molecules is described. Ni[N(SiMe3)(DIPP)]2 reacts with DMAP and acetonitrile to form T-shaped three-coordinate complexes, and preliminary results show that Ni[N(SiMe3)(DIPP)]2 is a catalyst for the hydrosilation of olefins with secondary silanes at ambient temperature.

Graphical abstract: Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(ii) complex

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Article information

DOI
https://doi.org/10.1039/C2CC32974C
Article type
Communication
Submitted
26 Apr 2012
Accepted
23 May 2012
First published
12 Jun 2012

Chem. Commun., 2012,48, 7146-7148

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Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(II) complex

M. I. Lipschutz and T. D. Tilley, Chem. Commun., 2012, 48, 7146 DOI: 10.1039/C2CC32974C

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