Issue 52, 2012
From the journal:

Chemical Communications

Gels of shape-persistent macrocycles: the role of the interior†

Joscha Vollmeyer,a   Stefan-S. Jester,*a   Friederike Eberhagen,a   Thomas Prangenberg,b   Werner Maderb  and  Sigurd Höger*a  

* Corresponding authors

a Rheinische Friedrich-Wilhelms-Universität Bonn, Kekulé-Institut für Organische Chemie und Biochemie, Gerhard-Domagk-Str. 1, 53121 Bonn, Germany
E-mail: stefan.jester@uni-bonn.de, hoeger@uni-bonn.de
Fax: +49 228 73 5662
Tel: +49 228 73 3495

b Rheinische Friedrich-Wilhelms-Universität Bonn, Institut für Anorganische Chemie, Römerstr. 164, 53117 Bonn, Germany

Abstract

The aggregation of shape-persistent macrocycles with an empty cavity, an undecyldiether strand and a tetraethylene glycol strand leads in all cases to a macroscopic gelation of the solvent. However, the gelation temperatures are fine-tuned by the intraannular substituents.

Graphical abstract: Gels of shape-persistent macrocycles: the role of the interior

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Article information

DOI
https://doi.org/10.1039/C2CC32804F
Article type
Communication
Submitted
19 Apr 2012
Accepted
09 May 2012
First published
10 May 2012

Chem. Commun., 2012,48, 6547-6549

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Gels of shape-persistent macrocycles: the role of the interior

J. Vollmeyer, Stefan-S. Jester, F. Eberhagen, T. Prangenberg, W. Mader and S. Höger, Chem. Commun., 2012, 48, 6547 DOI: 10.1039/C2CC32804F

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