The product of the reaction between C5H5Na and PtCl2 is shown by X-ray crystal structure analysis to consist of two π-cyclopentadienylplatinum units joined by a Pt–Pt bond and a bridging 5-cyclopentadienyl-cyclopentadiene unit.
K. K. Cheung, R. J. Cross, K. P. Forrest, R. Wardle and M. Mercer, J. Chem. Soc. D, 1971, 875 DOI: 10.1039/C29710000875
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