Issue 20, 1970

Mechanism of the baeyer–villiger reaction

Abstract

Examination of the effects of substituents on the rate and the migratory aptitude in the oxidation of substituted pp′-dimethoxybenzophenones with peroxy-benzoic acid in dichloroacetic acid to give aryl benzoates suggests that the rearrangement of peroxybenzoic acid—ketone adducts to esters is rate-determing.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1301-1302

Mechanism of the baeyer–villiger reaction

T. Mitsuhashi, H. Miyadera and O. Simamura, J. Chem. Soc. D, 1970, 1301 DOI: 10.1039/C29700001301

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