SCHEDULED MAINTENANCE
The crystal structure of tetrakis-(N-ethylsalicylaldiminato)zirconium(IV) contains eight-co-ordinated (dodecahedral) tetrachelated zirconium in the unusual S4 configuration with remarkably long Zr–N bond lengths; n.m.r. evidence suggests that the N-isopropyl derivative is also eight-co-ordinate whereas the N-t-butyl derivative involves a lower co-ordination of the zirconium.
D. C. Bradley, M. B. Hursthouse and I. F. Rendall, J. Chem. Soc. D, 1970, 368 DOI: 10.1039/C29700000368
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