Microwave spectra have been observed for two isotopic species of p-fluoroaniline: the molecule is found to be more non-planar than aniline itself and this result is interpreted in terms of there being π-mesomeric involvement of fluorine electrons with the ring system.
A. Hastie, D. G. Lister, R. L. McNeil and J. K. Tyler, J. Chem. Soc. D, 1970, 108 DOI: 10.1039/C29700000108
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