Issue 29, 2011
From the journal:

Chemical Communications

An l-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions†

Xiao Wu,a   Cheng He,a   Xiang Wu,a   Siyi Qua  and  Chunying Duan*a  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China
E-mail: cyduan@dlut.edu.cn

Abstract

A homochiral metal–organic triangle Co–Pro1 was achieved via self-assembly by incorporating a L-proline moiety within the corresponding ligand. Co–Pro1 comprised L-proline moieties as asymmetric catalytic active sites and a helical-like cavity, it worked as an asymmetric catalyst to prompt aldol reactions with size-, stereo- and enantioselectivity.

Graphical abstract: An l-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions

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Article information

DOI
https://doi.org/10.1039/C1CC11698C
Article type
Communication
Submitted
25 Mar 2011
Accepted
08 Jun 2011
First published
24 Jun 2011

Chem. Commun., 2011,47, 8415-8417

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An L-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions

X. Wu, C. He, X. Wu, S. Qu and C. Duan, Chem. Commun., 2011, 47, 8415 DOI: 10.1039/C1CC11698C

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