Substituent effect of R-isophthalates (R = –H, –CH3, –OCH3, –tBu, –OH, and –NO2) on the construction of CdII coordination polymers incorporating a dipyridyl tecton 2,5-bis(3-pyridyl)-1,3,4-oxadiazole

Jing Chen; Cheng-Peng Li; Miao Du

doi:10.1039/C0CE00555J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Substituent effect of R-isophthalates (R = –H, –CH₃, –OCH₃, –tBu, –OH, and –NO₂) on the construction of Cd^II coordination polymers incorporating a dipyridyl tecton 2,5-bis(3-pyridyl)-1,3,4-oxadiazole†

Jing Chen,^a Cheng-Peng Li^a and Miao Du*^a

Author affiliations

* Corresponding authors

^a College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin, P. R. China
E-mail: dumiao@public.tpt.tj.cn

Abstract

A series of Cd^II coordination polymers have been designed and hydrothermally synthesized by using a bent dipyridyl tecton 2,5-bis(3-pyridyl)-1,3,4-oxadiazole (3-bpo) and R-isophthalic acids (H₂ip-R; R = –H, –CH₃, –OCH₃, –tBu, –OH, and –NO₂), which exhibit diverse 1D and 2D polymeric coordination networks. The results demonstrate that the substituent effect of R-isophthalates does play a decisive role in directing the structural assemblies of this system, in which secondary interactions such as H-bonding and π⋯π stacking are generally observed to extend the coordination motifs. Notably, the 3-bpo building block shows adaptable conformations (cisoid-I, cisoid-II, and transoid) to facilitate the structural diversity of these complexes. Solid state properties such as thermal stability and fluorescence for these crystalline materials will also be presented.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C0CE00555J
Article type: Paper
Submitted: 20 Aug 2010
Accepted: 26 Oct 2010
First published: 14 Dec 2010

Download Citation

CrystEngComm, 2011,13, 1885-1893

Permissions

Request permissions

Substituent effect of R-isophthalates (R = –H, –CH₃, –OCH₃, –tBu, –OH, and –NO₂) on the construction of Cd^II coordination polymers incorporating a dipyridyl tecton 2,5-bis(3-pyridyl)-1,3,4-oxadiazole

J. Chen, C. Li and M. Du, CrystEngComm, 2011, 13, 1885 DOI: 10.1039/C0CE00555J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm