Issue 41, 2010
From the journal:

Chemical Communications

Amphiphilic photo-isomerisable phosphanes for aqueous organometallic catalysis†

Hervé Bricout,a   Estelle Banaszak,b   Christophe Len,b   Frédéric Hapiota  and  Eric Monflier*a  

* Corresponding authors

a Université de Lille Nord de France, CNRS UMR 8181, UArtois UCCS, Faculté des Sciences Jean Perrin, rue Jean Souvraz, SP 18, F-62307 Lens Cedex, France
E-mail: eric.monflier@univ-artois.fr
Fax: +33321791755
Tel: +33321791772

b Université de Technologie de Compiègne, Transformation Intégrées de la Matière Renouvelable, EA 4297 UTC/ESCOM, 1 allée du réseau Jean-Marie Buckmaster, F-60200 Compiègne, France

Abstract

Water-soluble phosphanes were tagged with a light-responding diazo group. Upon UV exposure, the diazo-isomerisation led to phosphane morphology change, resulting in an increase in the reaction rate of an aqueous palladium-catalysed cleavage reaction.

Graphical abstract: Amphiphilic photo-isomerisable phosphanes for aqueous organometallic catalysis

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Article information

DOI
https://doi.org/10.1039/C0CC02458A
Article type
Communication
Submitted
09 Jul 2010
Accepted
02 Sep 2010
First published
20 Sep 2010

Chem. Commun., 2010,46, 7813-7815

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Amphiphilic photo-isomerisable phosphanes for aqueous organometallic catalysis

H. Bricout, E. Banaszak, C. Len, F. Hapiot and E. Monflier, Chem. Commun., 2010, 46, 7813 DOI: 10.1039/C0CC02458A

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