Issue 1, 2011
From the journal:

Chemical Communications

Catalysts by the meter: rapid screening approach of N-heterocyclic carbeneligand based catalysts†‡

Carolin Lang,a   Ute Gärtnera  and  Oliver Trapp*a  

* Corresponding authors

a Ruprecht-Karls-Universität Heidelberg, Organisch-Chemisches Institut, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany
E-mail: trapp@oci.uni-heidelberg.de
Fax: +49 (0) 6221 544904
Tel: +49 (0) 6221 548470

Abstract

Here, we demonstrate a versatile screening platform for NHC ligand based catalysts by coating fused-silica micro capillaries with a bonded 1,3-bismesityl-2-imidazolidinylidene ligand. Such micro capillaries can be efficiently converted into (pre)-catalysts from various organometallic precursors by solid-phase chemistry techniques and can be quantitatively screened using on-column reaction chromatography.

Graphical abstract: Catalysts by the meter: rapid screening approach of N-heterocyclic carbene ligand based catalysts

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Article information

DOI
https://doi.org/10.1039/C0CC02306J
Article type
Communication
Submitted
01 Jul 2010
Accepted
24 Aug 2010
First published
08 Sep 2010

Chem. Commun., 2011,47, 391-393

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Catalysts by the meter: rapid screening approach of N-heterocyclic carbene ligand based catalysts

C. Lang, U. Gärtner and O. Trapp, Chem. Commun., 2011, 47, 391 DOI: 10.1039/C0CC02306J

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