Issue 1, 2011
From the journal:

Chemical Communications

Probing for non-statistical effects in dissociation of the 1-methylallyl radical†‡

Michael Gasser,a   Jann A. Frey,a   Jonas M. Hostettlera  and  Andreas Bach*a  

* Corresponding authors

a Laboratorium für Organische Chemie, Wolfgang-Pauli Strasse 10, ETH Zürich, Switzerland
E-mail: bach@org.chem.ethz.ch
Fax: +41 44 632 1280
Tel: +41 44 633 4785

Abstract

The 1-methylallyl radical loses a hydrogen atom following photoexcitation to its lowest valence electronically excited state and displays statistical behavior in decomposition, implying that the presence of methyl rotors cannot be depended upon as an indicator for non-statistical dissociation dynamics in hydrocarbon radicals.

Graphical abstract: Probing for non-statistical effects in dissociation of the 1-methylallyl radical

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Article information

DOI
https://doi.org/10.1039/C0CC01899F
Article type
Communication
Submitted
15 Jun 2010
Accepted
13 Jul 2010
First published
05 Aug 2010

Chem. Commun., 2011,47, 301-303

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Probing for non-statistical effects in dissociation of the 1-methylallyl radical

M. Gasser, J. A. Frey, J. M. Hostettler and A. Bach, Chem. Commun., 2011, 47, 301 DOI: 10.1039/C0CC01899F

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