Issue 1, 2011

A triangulopalladium cluster consisting of μ3-capping silyl ligands

Abstract

We report on the utility of multifunctional, κ1Si3S-coordinated tris(methimazolyl)silanide ligands [Si(mtMe)3] for the stabilisation of a triangulopalladium cluster [Pd3{Si(mtMe)3}2] (3) consisting of very unusual μ3-capping SiR3 donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.

Graphical abstract: A triangulopalladium cluster consisting of μ3-capping silyl ligands

Supplementary files

Article information

Article type
Communication
Submitted
04 Feb 2010
Accepted
14 Apr 2010
First published
28 Apr 2010

Chem. Commun., 2011,47, 221-223

A triangulopalladium cluster consisting of μ3-capping silyl ligands

F. Armbruster, J. Meyer, A. Baldes, P. O. Burgos, I. Fernández and F. Breher, Chem. Commun., 2011, 47, 221 DOI: 10.1039/C002435J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements