Issue 7, 2010

0D and 1D dimensional structures based on the combination of polyoxometalates, transition metal coordination complexes and organic amines

Abstract

Five novel heteropolyanions have been synthesized and characterized by IR, UV-vis, XPS spectroscopy, XRD, and elemental analyses. Single-crystal X-ray diffraction analyses reveal that these five compounds represent novel examples of compounds based on the combination of polyoxometalates, transition metal coordination complexes and organic amines. Of which 1, 2 and 3 exhibit 0D structures of polyoxometalate supported transition metal coordination complexes, while 4 and 5 exhibit novel 1D structures constructed from polyoxometalates and transition metal coordination complexes.

Graphical abstract: 0D and 1D dimensional structures based on the combination of polyoxometalates, transition metal coordination complexes and organic amines

Supplementary files

Article information

Article type
Paper
Submitted
21 Jul 2009
Accepted
23 Jan 2010
First published
16 Feb 2010

CrystEngComm, 2010,12, 2122-2128

0D and 1D dimensional structures based on the combination of polyoxometalates, transition metal coordination complexes and organic amines

S. Shi, Y. Zou, X. Cui, J. Xu, Y. Wang, G. Wang, G. Yang, J. Xu, T. Wang and Z. Gao, CrystEngComm, 2010, 12, 2122 DOI: 10.1039/B914655E

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