Issue 6, 2009

Cyano-bridged coordination polymernanoparticles

Abstract

A survey on the synthesis of cyano-bridged coordination polymer nanoparticles (CPNs) performed in our group and on the study of their related magnetic properties is given. Two synthetic approaches consisting in the one-pot synthesis of soluble CPNs and in the sequential growth of CPNs onto appropriate matrices are reviewed. A special emphasis is placed on the magnetic properties of CPNs and the determination of the magnetic regime in these systems, which strongly depends on various factors. We show that the size of the nanoparticles, the magnetostatic interparticles and/or the NP–matrix interactions provide significant modification of the superparamagnetic relaxation regime.

Graphical abstract: Cyano-bridged coordination polymer nanoparticles

Article information

Article type
Perspective
Submitted
15 Jan 2009
Accepted
07 Apr 2009
First published
27 Apr 2009

New J. Chem., 2009,33, 1177-1190

Cyano-bridged coordination polymer nanoparticles

J. Larionova, Y. Guari, C. Sangregorio and C. Guérin, New J. Chem., 2009, 33, 1177 DOI: 10.1039/B900918C

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