Stereoselective synthesis of (Z)-α-halo-α,β-unsaturated esters, and amides from aldehydes and trihaloesters or amides promoted by manganese

José M. Concellón; Humberto Rodríguez-Solla; Pamela Díaz

doi:10.1039/B717513B

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Stereoselective synthesis of (Z)-α-halo-α,β-unsaturated esters, and amides from aldehydes and trihaloesters or amides promoted by manganese†

José M. Concellón,*^a Humberto Rodríguez-Solla^a and Pamela Díaz^a

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* Corresponding authors

^a Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, Julián Clavería 8, 33071 Oviedo, Spain
E-mail: jmcg@uniovi.es

Abstract

Preliminary results of a Mn-promoted sequential process directed toward the stereoselective synthesis of different (Z)-α-halo-α,β-unsaturated compounds are described.

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Supplementary files

General procedures, spectroscopic data, and copies of ¹H and ¹³C NMR spectra for compounds 3, 5 and 9 PDF (968K)

Article information

DOI: https://doi.org/10.1039/B717513B
Article type: Communication
Submitted: 13 Nov 2007
Accepted: 11 Dec 2007
First published: 21 Dec 2007

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Org. Biomol. Chem., 2008,6, 451-453

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Stereoselective synthesis of (Z)-α-halo-α,β-unsaturated esters, and amides from aldehydes and trihaloesters or amides promoted by manganese

J. M. Concellón, H. Rodríguez-Solla and P. Díaz, Org. Biomol. Chem., 2008, 6, 451 DOI: 10.1039/B717513B

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Organic & Biomolecular Chemistry

Stereoselective synthesis of (Z)-α-halo-α,β-unsaturated esters, and amides from aldehydes and trihaloesters or amides promoted by manganese†

Abstract

Supplementary files

Article information

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Stereoselective synthesis of (Z)-α-halo-α,β-unsaturated esters, and amides from aldehydes and trihaloesters or amides promoted by manganese

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