Issue 1, 2008
From the journal:

New Journal of Chemistry

Synthesis and X-ray structures of cadmium-containing dinuclear double helicates derived from ligands containing N-oxide units

Georgios Bokolinis,a   T. Riis-Johannessen,†b   John C. Jefferyb  and  Craig R. Rice*a  

* Corresponding authors

a Department of Chemical and Biological Sciences, University of Huddersfield, Huddersfield, UK
E-mail: c.r.rice@hud.ac.uk
Fax: (+44)1484 472182
Tel: (+44)1484 473759

b School of Chemistry, University of Bristol, Cantocks Close, Bristol, UK

Abstract

The syntheses of two novel polydentate pyridyl-thiazolyl ligands which contain an N-oxide unit on the central pyridyl ring are reported. Reaction of either of these ligands with Cd(ClO4)2·6H2O results in the formation of a dinuclear double helicate. The solid state structures of these transition metal helicates demonstrate the ability of the N-oxide unit to partition the ligands into two separate binding domains.

Graphical abstract: Synthesis and X-ray structures of cadmium-containing dinuclear double helicates derived from ligands containing N-oxide units

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Article information

DOI
https://doi.org/10.1039/B711039A
Article type
Paper
Submitted
18 Jul 2007
Accepted
30 Aug 2007
First published
07 Sep 2007

New J. Chem., 2008,32, 115-119

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Synthesis and X-ray structures of cadmium-containing dinuclear double helicates derived from ligands containing N-oxide units

G. Bokolinis, T. Riis-Johannessen, J. C. Jeffery and C. R. Rice, New J. Chem., 2008, 32, 115 DOI: 10.1039/B711039A

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