Issue 42, 2007

Insights into the relationship between inherent materials properties of PZT and photochemistry for the development of nanostructured silver

Abstract

Recently there has been great interest in using patterned ferroelectric materials for the photochemical growth of metal nanostructures. Variations in surface and sub-surface structure influence the photochemical processes. Here we show that crystallography, and hence remnant polarization, of the ferroelectric affects photo-deposition. The ratio of metal growth on cāˆ’ and c+ domains varies from 1 : 2 for [100] to 1 : 100 for [111]. This is shown to be dependent on the variations in the band structure.

Graphical abstract: Insights into the relationship between inherent materials properties of PZT and photochemistry for the development of nanostructured silver

Article information

Article type
Communication
Submitted
16 Jul 2007
Accepted
14 Sep 2007
First published
25 Sep 2007

J. Mater. Chem., 2007,17, 4460-4463

Insights into the relationship between inherent materials properties of PZT and photochemistry for the development of nanostructured silver

S. Dunn, D. Tiwari, P. M. Jones and D. E. Gallardo, J. Mater. Chem., 2007, 17, 4460 DOI: 10.1039/B710894J

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