Issue 23, 2006
From the journal:

Chemical Communications

Preparation, crystallographic characterization and theoretical study of C70(CF3)16 and C70(CF3)18†

Stanislav M. Avdoshenko,a   Alexey A. Goryunkov,a   Ilya N. Ioffe,a   Daria V. Ignat'eva,a   Lev N. Sidorov,a   Philip Pattison,bc   Erhard Kemnitzd  and  Sergey I. Troyanov*a  

* Corresponding authors

a Chemistry Department, Moscow State University, Leninskie Gory, Russia
E-mail: sergej.troyanov@rz.hu-berlin.de
Fax: +7 495 9391240
Tel: +7 495 9394596

b Swiss-Norwegian Beamline, European Synchrotron Radiation Facility, BP 220, Grenoble, France

c École Polytechnique Fédéral de Lausanne, Laboratoire de cristallographie, BSP, Switzerland

d Institute of Chemistry, Humboldt University Berlin, Brook-Taylor-Str. 2, Germany

Abstract

C70(CF3)16 and C70(CF3)18, the first trifluoromethylated fullerene derivatives to comprise a pair of adjacent CF3 groups, have been isolated from a mixture obtained via reaction of C70 with CF3I, characterized in a single crystal XRD study and theoretically investigated at the DFT level of theory.

Graphical abstract: Preparation, crystallographic characterization and theoretical study of C70(CF3)16 and C70(CF3)18

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Article information

DOI
https://doi.org/10.1039/B603201J
Article type
Communication
Submitted
03 Mar 2006
Accepted
13 Apr 2006
First published
03 May 2006

Chem. Commun., 2006, 2463-2465

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Preparation, crystallographic characterization and theoretical study of C70(CF3)16 and C70(CF3)18

S. M. Avdoshenko, A. A. Goryunkov, I. N. Ioffe, D. V. Ignat'eva, L. N. Sidorov, P. Pattison, E. Kemnitz and S. I. Troyanov, Chem. Commun., 2006, 2463 DOI: 10.1039/B603201J

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