Issue 2, 2006
From the journal:

CrystEngComm

Supramolecular architectures of neutral and cationic complexes of transition metals with lactate and 1,10-phenanthroline

Berta Covelo,*a   Rosa Carballo,*a   Ezequiel M. Vázquez-López,a   Emilia García-Martínez,a   Alfonso Castiñeiras,b   Susana Balboab  and  Juan Niclósc  

* Corresponding authors

a Departamento de Química Inorgánica. Facultade de Química. Universidade de Vigo., Vigo, Spain
E-mail: bcovelo@uvigo.es, rcrial@uvigo.es

b Departamento de Química Inorgánica. Facultade de Farmacia. Universidade de Santiago de Compostela., Santiago de Compostela, Spain

c Departamento de Química Inorgánica. Facultad de Farmacia. Universidad de Granada., Granada, Spain

Abstract

The following molecular complexes of transition metals MII with lactato (HL) and 1,10-phenanthroline (phen) ligands were prepared and characterized structurally: [M(HL)2(phen)]·nH2O, MII = Mn, Co, Ni, Cu, Zn; 1–6), [M(HL)(H2O)2(phen)]Cl, (MII = Mn, Co, Ni; 7–9), and [Ni(HL)(H2O)2(phen)]Br (10). These neutral and cationic octahedral complexes have 3-D supramolecular architectures due to weak noncovalent interactions. In the halide compounds, C–H⋯X− hydrogen bonds play a key role in the stabilization of the 3-D network.

Graphical abstract: Supramolecular architectures of neutral and cationic complexes of transition metals with lactate and 1,10-phenanthroline

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Article information

DOI
https://doi.org/10.1039/B515539H
Article type
Paper
Submitted
01 Nov 2005
Accepted
24 Jan 2006
First published
08 Feb 2006

CrystEngComm, 2006,8, 167-177

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Supramolecular architectures of neutral and cationic complexes of transition metals with lactate and 1,10-phenanthroline

B. Covelo, R. Carballo, E. M. Vázquez-López, E. García-Martínez, A. Castiñeiras, S. Balboa and J. Niclós, CrystEngComm, 2006, 8, 167 DOI: 10.1039/B515539H

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