Issue 115, 2005
From the journal:

CrystEngComm

Hydrogen-bonded networks from novel platinum(ii) dimers

Michael Carland,a   Brendan F. Abrahams,*a   William A. Denny,c   Vincent Murrayb  and  W. David McFadyen*a  

* Corresponding authors

a School of Chemistry, The University of Melbourne, Victoria, Australia

b School of Biochemistry and Molecular Genetics, University of New South Wales, Sydney, NSW, Australia

c Auckland Cancer Society Research Centre, Faculty of Medicine and Health Science, The University of Auckland, Private Bag 92019, Auckland, New Zealand

Abstract

The structures of the complexes: cis-dichloro[(2-(phenylselanyl)ethanamine]platinum(II) (1) and cis-dichloro[(2-(benzylyselanyl)ethanamine]platinum(II) (2) are reported. Self-complementary N–H⋯Cl interactions result in the generation of dimers. Through this dimerization the Pt centres are brought within 3.4905(5) Å in the case of 1 and 3.6142(6) Å in the case of 2. When each of the dimers is viewed along the Pt–Pt vector the Pt to donor atom bonds are eclipsed. Through further N–H⋯Cl interactions, 1 forms a chain while 2 forms a sheet.

Graphical abstract: Hydrogen-bonded networks from novel platinum(ii) dimers

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Article information

DOI
https://doi.org/10.1039/B511536A
Article type
Paper
Submitted
12 Aug 2005
Accepted
17 Nov 2005
First published
25 Nov 2005

CrystEngComm, 2005,7, 701-705

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Hydrogen-bonded networks from novel platinum(II) dimers

M. Carland, B. F. Abrahams, W. A. Denny, V. Murray and W. D. McFadyen, CrystEngComm, 2005, 7, 701 DOI: 10.1039/B511536A

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