Issue 2, 2004
From the journal:

Journal of Materials Chemistry

Bulk synthesis and characterization of graphite-like B–C–N and B–C–N heterodiamond compounds

Tamikuni Komatsua  

a c/o The Noguchi Institute, Asahi Kasei Corporation, 1-8-1 Kaga, Itabashi-ku, Tokyo, Japan
E-mail: BRA01367@nifty.ne.jp

Abstract

High quality graphite-like B–C–N compounds used for the shock-synthesis of B–C–N heterodiamonds were bulk-synthesized in good yield by pyrolysis of the polymers between BCl3 and commercially available nitriles at 1773 K. It was elucidated that the series of obtained heterodiamond compounds are described by the formula CBxNx(BN)y composed of CBxNx and (BN)y segments and have an unusual structure in which diamond-like carbon atoms are randomly substituted for B/N atoms and (BN)y segments, based on IR, XPS and X-ray powder diffraction.

Graphical abstract: Bulk synthesis and characterization of graphite-like B–C–N and B–C–N heterodiamond compounds

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Article information

DOI
https://doi.org/10.1039/B310513J
Article type
Paper
Submitted
29 Aug 2003
Accepted
05 Nov 2003
First published
12 Dec 2003

J. Mater. Chem., 2004,14, 221-227

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Bulk synthesis and characterization of graphite-like B–C–N and B–C–N heterodiamond compounds

T. Komatsu, J. Mater. Chem., 2004, 14, 221 DOI: 10.1039/B310513J

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