Issue 8, 2003
From the journal:

Chemical Communications

One- and three-dimensional infinite arrays of Cu(i) ions exhibited by [Cu(NH3)2]Br and [Cu(NH3)Cl] in the solid state

Günter Margraf,a   Jan W. Bats,b   Michael Bolte,b   Hans-Wolfram Lernera  and  Matthias Wagner*a  

* Corresponding authors

a Institut für Anorganische Chemie, J.W. Goethe-Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt (Main), Germany
E-mail: Matthias.Wagner@chemie.uni-frankfurt.de
Fax: +49 69 798 29260

b Institut für Organische Chemie, J.W. Goethe-Universität Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt (Main), Germany

Abstract

In the solid state, [Cu(NH3)Cl] forms a three-dimensional network with each CuI ion being surrounded by three other CuI centres in a trigonal-planar fashion [Cu⋯Cu = 2.979(1) Å; cubic space group I213], whereas in [Cu(NH3)2]Br the cations establish infinite linear (Cu⋯Cu)∞ chains spanning the crystal lattice [Cu⋯Cu = 2.931(1) Å; monoclinic space group C2/c].

Graphical abstract: One- and three-dimensional infinite arrays of Cu(i) ions exhibited by [Cu(NH3)2]Br and [Cu(NH3)Cl] in the solid state

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Article information

DOI
https://doi.org/10.1039/B212517J
Article type
Communication
Submitted
23 Dec 2002
Accepted
14 Feb 2003
First published
11 Mar 2003

Chem. Commun., 2003, 956-957

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One- and three-dimensional infinite arrays of Cu(I) ions exhibited by [Cu(NH3)2]Br and [Cu(NH3)Cl] in the solid state

G. Margraf, J. W. Bats, M. Bolte, H. Lerner and M. Wagner, Chem. Commun., 2003, 956 DOI: 10.1039/B212517J

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