Issue 6, 2003
From the journal:

Chemical Communications

The first example of enantioselective isocyanosilylation of mesoepoxides with TMSCN catalyzed by novel chiral organogallium and indium complexes†

Chengjian Zhu,*ab   Fang Yuan,a   Weijin Gua  and  Yi Pan*a  

* Corresponding authors

a Department of Chemistry, Nanjing University, Nanjing 210093, China
E-mail: cjzhu@netra.nju.edu.cn and yipan@nju.edu.cn.

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

The desymmetrization ring opening of meso epoxides using trimethylsilyl cyanide catalyzed by organogallium and indium complexes with binaphthol monoether derivatives as chiral ligands gave β-isocyanohydrins with moderate to excellent enantioselectivities of up to 95% ee.

Graphical abstract: The first example of enantioselective isocyanosilylation of meso epoxides with TMSCN catalyzed by novel chiral organogallium and indium complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B212511K
Article type
Communication
Submitted
17 Dec 2002
Accepted
24 Jan 2003
First published
13 Feb 2003

Chem. Commun., 2003, 692-693

Permissions

Request permissions

The first example of enantioselective isocyanosilylation of meso epoxides with TMSCN catalyzed by novel chiral organogallium and indium complexes

C. Zhu, F. Yuan, W. Gu and Y. Pan, Chem. Commun., 2003, 692 DOI: 10.1039/B212511K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements