Issue 16, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and structure of [2-{4(S)-isopropyl-2-oxazolinyl}phenyl]trimethyl tin and its reactivity as a carbometallating agent

Adam J. Davenport,a   David L. Davies,*a   John Fawcetta  and  David R. Russella  

* Corresponding authors

a Department of Chemistry, University of Leicester, Leicester, UK

Abstract

Reaction of LiL 3c (LH = 4(S)-isopropyl-2-oxazolinylbenzene) with Me3SnCl affords LSnMe33d. Attempts to transfer the oxazolinylphenyl to [RuCl2(mes)]2 or [RhCl2Cp*]2 using 3d failed, in both cases there is evidence for transfer of methyl with the formation of LSnMe2Cl 5. Reaction of 3d with [PdCl2(PhCN)2] leads to selective transfer of the aryloxazoline, forming [LPdCl]26 which has been prepared independently via metathesis of [LPd(OAc)]27 with lithium chloride. However, the reaction of 3d with [PdCl2(COD)] is not selective, transfer of both methyl and aryl occurring. The structures of 3d, 5 and 7 have been determined by X-ray diffraction.

Graphical abstract: Synthesis and structure of [2-{4(S)-isopropyl-2-oxazolinyl}phenyl]trimethyl tin and its reactivity as a carbometallating agent

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B202405E
Article type
Paper
Submitted
08 Mar 2002
Accepted
12 Jun 2002
First published
17 Jul 2002

J. Chem. Soc., Dalton Trans., 2002, 3260-3264

Permissions

Request permissions

Synthesis and structure of [2-{4(S)-isopropyl-2-oxazolinyl}phenyl]trimethyl tin and its reactivity as a carbometallating agent

A. J. Davenport, D. L. Davies, J. Fawcett and D. R. Russell, J. Chem. Soc., Dalton Trans., 2002, 3260 DOI: 10.1039/B202405E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements