All four possible stereoisomers of lactone II isolated from Streptomyces sp. Go 40/10, an autoregulator, have been efficiently synthesized in a stereoselective manner starting from (S)-malic acid and sorbic acid, and the absolute configuration was determined to be 2S, 3S, 9R, 10S.
Synthesis and absolute configuration of lactone II isolated from Streptomyces sp. Go 40/10
T. Ueki, Y. Morimoto and T. Kinoshita, Chem. Commun., 2001, 1820 DOI: 10.1039/B104920H
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