Issue 19, 2000
From the journal:

Chemical Communications

On the reductive amination of aldehydes and ketones catalyzed by homogeneous Rh(i) complexes

Vitali I. Tararov,a   Renat Kadyrov,a   Thomas H. Riermeierc  and  Armin Börner*a  

* Corresponding authors

a Institut für Organische Katalyseforschung an der Universität Rostock e.V., Buchbinderstr. 5/6, D-18055, Rostock, Germany.
E-mail: armin.boerner@ifok.uni-rostock.de

b A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova 28, 117813, Moscow, Russian Federation

c Aventis Research & Technologies GmbH Industriepark Höchst, G 830, D-65926, Frankfurt/Main, Germany

Abstract

The homogeneously catalyzed reductive amination of aldehydes and ketones under smooth conditions is reported, showing for the first time, that Rh(I) catalysts based on chelating diphosphines and diphosphinites can be advantageously employed for this reaction, even for the production of chiral amino acid derivatives.

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Article information

DOI
https://doi.org/10.1039/B005777K
Article type
Communication
Submitted
18 Jul 2000
Accepted
15 Aug 2000
First published
15 Sep 2000

Chem. Commun., 2000, 1867-1868

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On the reductive amination of aldehydes and ketones catalyzed by homogeneous Rh(I) complexes

V. I. Tararov, R. Kadyrov, T. H. Riermeier and A. Börner, Chem. Commun., 2000, 1867 DOI: 10.1039/B005777K

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