Issue 7, 1998
From the journal:

New Journal of Chemistry

A novel binuclear rhodium complex with two mercapto bridges and two terminal thioether groups

Francesc Teixidor,   M. Rosa Cirera,   Clara Viñas,   Raikko Kivekäs,   Reijo Sillanpää  and  Joan Llibre  

Abstract

The cyclic thioether–thioester ligand [7,8-µ-SCH2C(O)S-7,8-C2B9H10]-, [L1]-, is a source of strongly co-ordinating mercapto and thioether groups. Upon reaction with complexes with metal ions in oxidation state higher than+1, [L1]- modifies to the dianionic ligand [7-S,8-SCH2C(O)OMe-7,8-C2B9H10]2-, [L2]2-. Reaction of [NMe4][L1] with [M2(C5Me5)2Cl4] (M=RhIII or IrIII) in MeOH produces [M2(C5Me5)2(L2)2], a molecule with an earmuff shape.

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Article information

DOI
https://doi.org/10.1039/A803026J
Article type
Paper

New J. Chem., 1998,22, 665-666

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A novel binuclear rhodium complex with two mercapto bridges and two terminal thioether groups

F. Teixidor, M. Rosa Cirera, C. Viñas, R. Kivekäs, R. Sillanpää and J. Llibre, New J. Chem., 1998, 22, 665 DOI: 10.1039/A803026J

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