Issue 24, 1997
From the journal:

Chemical Communications

Macropolyhedral boron-containing cluster chemistry. Triple cluster fusion and the molecular structure of [(PMe3)2IrB26H24Ir(CO)(PMe3)2]. A 28-vertex metallaborane cluster with a polyboron core†

Jonathan Bould,   John D. Kennedy,   Jonathan Bould,   Lawrence Barton  and  Nigam P. Rath  

Abstract

[(PMe3)2IrB26H24Ir(CO)(PMe3)2], from the thermolysis of [(CO)(PMe3)2HIrB8H12] in molten B10H14, is a triple-cluster species that consists of closo twelve-vertex {IrB11} and closo ten-vertex {IrB9} units fused by (a) a common {IrB2} triangular face and (b) by an adjacent ‘wedge’ interboron linkage that also binds a nido nine-vertex {IrB8} subcluster; the resulting {Ir2B26} cluster has a novel five-boron core.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/A706905G
Article type
Paper

Chem. Commun., 1997, 2405-2406

Permissions

Request permissions

Macropolyhedral boron-containing cluster chemistry. Triple cluster fusion and the molecular structure of [(PMe3)2IrB26H24Ir(CO)(PMe3)2]. A 28-vertex metallaborane cluster with a polyboron core†

J. Bould, J. D. Kennedy, J. Bould, L. Barton and N. P. Rath, Chem. Commun., 1997, 2405 DOI: 10.1039/A706905G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements