Issue 5, 1998

Remote stereocontrol as a synthetic strategy: diastereoselective annulations on an arene tricarbonylchromium template

Abstract

Stereoselective annulations on Cr(CO)3 complexed tetralone and benzosuberone § derivatives have been achieved. Diastereomeric products are shown to be related by an epimerisable chiral centre. An unusually facile de-ethoxycarbonylation has been observed.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1998, 977-982

Remote stereocontrol as a synthetic strategy: diastereoselective annulations on an arene tricarbonylchromium template

S. Sur, S. Ganesh, V. G. Puranik and A. Sarkar, J. Chem. Soc., Perkin Trans. 1, 1998, 977 DOI: 10.1039/A705285E

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