A synthesis of a carbotricycle related to the phorbol skeleton has been achieved in five steps hinging upon an unusual intramolecular Diels–Alder reaction; a usefully oxygenated diene subunit is introduced by a palladium catalysed coupling.
P. C. B. Page and D. C. Jennens, J. Chem. Soc., Perkin Trans. 1, 1992, 2587 DOI: 10.1039/P19920002587
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