Issue 0, 1974

Aryne chemistry. Part XXXV. Reactions of arynes with 1-aminocycloalkenes and hydrolyses of the adducts

Abstract

Reactions of benzyne and tetrahalogenobenzynes with 1-dialkylaminocycloalkenes afford the expected benzocyclobutene derivatives. The hydrolysis of these compounds in the presence of aqueous acid proceeds by C–aryl bond cleavage in the case of the tetrahalogeno-compounds whereas in the hydrolysis of 4b-pyrrolidin-1-yloctahydrobenzo[3,4]cyclobuta[1,2]cyclo-octene, C(4b)–C(10a) bond cleavage is observed

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1974, 2693-2694

Aryne chemistry. Part XXXV. Reactions of arynes with 1-aminocycloalkenes and hydrolyses of the adducts

H. Heaney and S. V. Ley, J. Chem. Soc., Perkin Trans. 1, 1974, 2693 DOI: 10.1039/P19740002693

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