Issue 0, 1966
From the journal:

Journal of the Chemical Society B: Physical Organic

Molecular polarisability. The anisotropic polarisability of the C[triple bond, length as m-dash]C bond

R. J. W. Le Fèvre,   B. J. Orr  and  G. L. D. Ritchie  

Abstract

Dipole moments and molar Kerr constants at 25° are recorded for 3-chloropropyne, 3-bromopropyne, phenylacetylene, diphenylacetylene, di-(p-chlorophenyl)acetylene, and dimethyl and diethyl acetylenedicarboxylate, as solutes in carbon tetrachloride. Anisotropic polarisabilities (bL= 3·79, bT=bv= 1·26) for the C≡C bond, deduced from literature data, are satisfactorily applicable to 3-chloropropyne, 3-bromopropyne, and phenylacetylene. Observations on the esters can be interpreted in terms of a mixture of non-planar cis- and trans-isomers.

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Article information

DOI
https://doi.org/10.1039/J29660000281
Article type
Paper

J. Chem. Soc. B, 1966, 281-284

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Molecular polarisability. The anisotropic polarisability of the C[triple bond, length as m-dash]C bond

R. J. W. Le Fèvre, B. J. Orr and G. L. D. Ritchie, J. Chem. Soc. B, 1966, 281 DOI: 10.1039/J29660000281

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