Issue 16, 1992

Absolute uranium–ligand bond-disruption enthalpies of [U(C5H4R)3X] complexes (X = I or H, R = But or SiMe3)

Abstract

The absolute uranium–ligand bond-disruption enthalpies (kJ mol–1) of the series [U(C5H4R)3X](X = H or I, R = But or SiMe3) have been measured by iodinolysis batch-titration solution calorimetry in toluene: R = But, 246.3 ± 5.3 (X = I), 249.7 ± 5.7 (X = H); R = SiMe3, 265.6 ± 4.3 (X = I), 251.7 ± 5.1 (X = H).

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 2439-2440

Absolute uranium–ligand bond-disruption enthalpies of [U(C5H4R)3X] complexes (X = I or H, R = But or SiMe3)

X. Jemine, J. Goffart, J. Berthet and M. Ephritikhine, J. Chem. Soc., Dalton Trans., 1992, 2439 DOI: 10.1039/DT9920002439

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements