Issue 8, 1990
From the journal:

Journal of the Chemical Society, Dalton Transactions

Iron-57 Mössbauer spectroscopic studies on 1,1′-bis(diphenylphosphino)ferrocene metal complexes. The influence of metal-ion geometry on the hyperfine interactions

Andrew Houlton,   Sahd K. Ibrahim,   Jonathan R. Dilworth  and  Jack Silver  

Abstract

57 Fe Mössbauer spectroscopic data for a series of 1,1′-bis(diphenylphosphino)ferrocene metal complexes [Fe(η-C5H4PPh2)2MXn](X = halide or CO, n= 2 or 4) are reported. An approximately linear correlation was found between the isomer shift (δ) and the quadrupole splitting (Δ). Moreover, complexes of like co-ordination geometry fell within exclusive domains on a plot of δvs.Δ. The results of an analysis of available crystal-structure data are consistent with these observations. The Mössbauer hyperfine interactions are discussed in relation to the geometry of the co-ordinated metal.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9900002421
Article type
Paper

J. Chem. Soc., Dalton Trans., 1990, 2421-2424

Permissions

Request permissions

Iron-57 Mössbauer spectroscopic studies on 1,1′-bis(diphenylphosphino)ferrocene metal complexes. The influence of metal-ion geometry on the hyperfine interactions

A. Houlton, S. K. Ibrahim, J. R. Dilworth and J. Silver, J. Chem. Soc., Dalton Trans., 1990, 2421 DOI: 10.1039/DT9900002421

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements