Issue 8, 1984

The vibrational spectrum of a strong O–H ⋯ F hydrogen bond: infrared and Raman spectra of the potassium fluoride–succinic acid adduct

Abstract

The crystalline potassium fluoride–succinic acid adduct contains strong hydrogen bonds, O–H ⋯ F. The i.r. spectra of KF·(CH2CO2H)2 and KF·(CH2CO2D)2 in the range 3 500–250 cm–1, and the Raman spectrum of the protonated adduct between 3 000 and 20 cm–1 are analysed in terms of the site symmetry in the crystal and are discussed according to current theories of the strong hydrogen bond.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1984, 1625-1628

The vibrational spectrum of a strong O–H ⋯ F hydrogen bond: infrared and Raman spectra of the potassium fluoride–succinic acid adduct

D. J. Jones, J. Emsley and J. Rozière, J. Chem. Soc., Dalton Trans., 1984, 1625 DOI: 10.1039/DT9840001625

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