SCHEDULED MAINTENANCE
Thermal hysteresis of stress and strain in spin-crossover@polymer composites: towards a rational design of actuator devices†
Abstract
Polymer composites of molecular spin crossover complexes have emerged as promising mechanical actuator materials, but their effective thermomechanical properties remain elusive. In this work, we investigated a series of iron(II)-triazole@P(VDF-TrFE) particulate composites using a tensile testing stage with temperature control. From these measurements, we assessed the temperature dependence of the Young's modulus as well as the free deformation and blocking stress, associated with the thermally-induced spin transition. The results denote that the expansion of the particles at the spin transition is effectively transferred to the macroscopic composite material, providing ca. 1–3% axial strain for 25% particle load. This strain is in excess of the ‘neat’ particle strain, which we attribute to particle-matrix mechanical coupling. On the other hand, the blocking stress (∼1 MPa) appears reduced by the softening of the composite around the spin transition temperature.
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