Issue 20, 2021

RuP2-based hybrids derived from MOFs: highly efficient pH-universal electrocatalysts for the hydrogen evolution reaction

Abstract

Rational design of efficient, low-cost, and durable electrocatalysts for the hydrogen evolution reaction (HER) in various pH media is highly desirable but remains challenging. Herein, for the first time, we present a novel hybrid of ruthenium diphosphide encapsulated in P-doped porous carbon (denoted as RuP2@PC) utilizing metal–organic frameworks (MOFs) as templates by a multi-step strategy. Unexpectedly, benefitting from the synergistic contribution of highly dispersed ultrafine RuP2 nanoparticles, porous carbon skeleton, and P-dopant, the as-synthesized RuP2@PC exhibits exceptional catalytic activity and superior durability as pH-universal electrocatalysts for the HER. Particularly, a low overpotential of 78.9 mV to deliver a current density of 10 mA cm−2 and a small Tafel slope of 36.7 mV dec−1 can be achieved in 1.0 M KOH toward the HER. Such outstanding electrocatalytic properties exceed those of commercial Pt/C and rank the catalyst among the best HER electrocatalysts reported until now. Importantly, this work paves a new route in elaborately fabricating efficient and stable electrocatalysts based on MOFs for energy-related fields.

Graphical abstract: RuP2-based hybrids derived from MOFs: highly efficient pH-universal electrocatalysts for the hydrogen evolution reaction

Supplementary files

Article information

Article type
Paper
Submitted
03 Mar 2021
Accepted
30 Apr 2021
First published
03 May 2021

J. Mater. Chem. A, 2021,9, 12276-12282

RuP2-based hybrids derived from MOFs: highly efficient pH-universal electrocatalysts for the hydrogen evolution reaction

J. Li, M. Huang, Y. Zhou, X. Chen, S. Yang, J. Zhu, G. Liu, L. Ma, S. Cai and J. Han, J. Mater. Chem. A, 2021, 9, 12276 DOI: 10.1039/D1TA01868J

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