Issue 19, 2021

Dipolar HCP materials as alternatives to DMF solvent for azide-based synthesis

Abstract

Hypercrosslinked polymers HCP-DMF and HCP-DMF-SO3H containing abundant and flexible DMF moieties were designed and synthesized. Benefitting from the solvation microenvironment provided by the pseudo-DMF moities, the polar HCPs manifested outstanding performances in the conversions of NaN3 to benzylic azides and 1,2,3-triazoles in EtOH (95%), respectively, avoiding the use of risky DMF and improving the separation processes of the products.

Graphical abstract: Dipolar HCP materials as alternatives to DMF solvent for azide-based synthesis

Supplementary files

Article information

Article type
Communication
Submitted
06 Jun 2021
Accepted
10 Aug 2021
First published
11 Aug 2021

Green Chem., 2021,23, 7499-7505

Dipolar HCP materials as alternatives to DMF solvent for azide-based synthesis

F. Gao, R. Bai, M. Li and Y. Gu, Green Chem., 2021, 23, 7499 DOI: 10.1039/D1GC02002A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements