Issue 17, 2021
From the journal:

Dalton Transactions

Metalloligands based on Robson-type amino-thiophenolato macrocycles for assembly of heterotrimetallic complexes†

Sara Schmorl,a   Sergej Naumov,b   Bernd Abel, ORCID logo bc   Martin Börner,ab   Andreas Pöppld  and  Berthold Kersting ORCID logo *a  

* Corresponding authors

a Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, 04103 Leipzig, Germany
E-mail: b.kersting@uni-leipzig.de
Fax: +49(0)341-97-3619

b Leibniz-Institut für Oberflächenmodifizierung (IOM), Abteilung Funktionale Oberflächen, Permoserstr. 15, D-04318 Leipzig, Germany

c Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstraße 2, D-04103 Leipzig, Germany

d Fakultät für Physik und Geowissenschaften, Linnestr.3, D-04103 Leipzig, Germany

Abstract

The ability of macrocyclic Co and Ni aminothiolate complexes to act as metalloligands towards cuprate ions was established. Adduct formation is enabled by a thiolate-to-Cu+ charge transfer (CT) interaction giving stable heterotrimetallics with magnetic properties.

Graphical abstract: Metalloligands based on Robson-type amino-thiophenolato macrocycles for assembly of heterotrimetallic complexes

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Article information

DOI
https://doi.org/10.1039/D1DT00723H
Article type
Communication
Submitted
03 Mar 2021
Accepted
11 Apr 2021
First published
14 Apr 2021

Dalton Trans., 2021,50, 5784-5788

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Metalloligands based on Robson-type amino-thiophenolato macrocycles for assembly of heterotrimetallic complexes

S. Schmorl, S. Naumov, B. Abel, M. Börner, A. Pöppl and B. Kersting, Dalton Trans., 2021, 50, 5784 DOI: 10.1039/D1DT00723H

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