Issue 28, 2019
From the journal:

New Journal of Chemistry

Further studies on the photoreactivities of ruthenium–nitrosyl complexes with terpyridyl ligands†

Isabelle Sasaki, ORCID logo ‡*a   Silvia Amabilino,a   Sonia Mallet-Ladeira,a   Marine Tassé,a   Alix Sournia-Saquet,a   Pascal G. Lacroix ORCID logo a  and  Isabelle Malfant ORCID logo *a  

* Corresponding authors

a LCC, UPR 8241, 205 route de Narbonne, 31077 Toulouse Cedex, France
E-mail: isabelle.sasaki@u-bordeaux.fr, isabelle.malfant@lcc-toulouse.fr

Abstract

This study focuses on the two cis/trans-(Cl,Cl)-[Ru(R-Phtpy)Cl2(NO)]+ isomers, where the R group is a NEt2 substituent on the 4′-position of the phenylterpyridine (Phtpy) moiety. The photophysical characteristic properties of the two isomers and those of one nitrosamine derivative are described. The NO release properties are evaluated and show that the cis isomer is the most efficient with a good quantum yield of NO release. The X-ray structures of three ruthenium–nitrosyl complexes and of a photoproduct are presented.

Graphical abstract: Further studies on the photoreactivities of ruthenium–nitrosyl complexes with terpyridyl ligands

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Article information

DOI
https://doi.org/10.1039/C9NJ02398D
Article type
Paper
Submitted
09 May 2019
Accepted
21 Jun 2019
First published
21 Jun 2019

New J. Chem., 2019,43, 11241-11250

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Further studies on the photoreactivities of ruthenium–nitrosyl complexes with terpyridyl ligands

I. Sasaki, S. Amabilino, S. Mallet-Ladeira, M. Tassé, A. Sournia-Saquet, P. G. Lacroix and I. Malfant, New J. Chem., 2019, 43, 11241 DOI: 10.1039/C9NJ02398D

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