Issue 27, 2018
From the journal:

Dalton Transactions

Hydrophosphination of alkenes and alkynes with primary phosphines catalyzed by zirconium complexes bearing aminophenolato ligands†

Yu Zhang,a   Xinxin Wang,a   Yaorong Wang, ORCID logo a   Dan Yuan ORCID logo *a  and  Yingming Yao ORCID logo *a  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Dushu Lake Campus, Soochow University, Suzhou 215123, P. R. China
E-mail: yuandan@suda.edu.cn, yaoym@suda.edu.cn

Abstract

Zirconium complexes stabilized by amine-bridged bis(phenolato) ligands showed good activity and chemo-selectivity in catalyzing intermolecular hydrophosphination of C–C multiple bonds with primary phosphines under mild conditions. A broad range of alkenes and alkynes underwent a mono-addition reaction with phenylphosphine, which generated secondary phosphines in 39–99% yields and >7 : 1 selectivity (over double hydrophosphination).

Graphical abstract: Hydrophosphination of alkenes and alkynes with primary phosphines catalyzed by zirconium complexes bearing aminophenolato ligands

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Article information

DOI
https://doi.org/10.1039/C8DT02122H
Article type
Paper
Submitted
24 May 2018
Accepted
16 Jun 2018
First published
19 Jun 2018

Dalton Trans., 2018,47, 9090-9095

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Hydrophosphination of alkenes and alkynes with primary phosphines catalyzed by zirconium complexes bearing aminophenolato ligands

Y. Zhang, X. Wang, Y. Wang, D. Yuan and Y. Yao, Dalton Trans., 2018, 47, 9090 DOI: 10.1039/C8DT02122H

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