SCHEDULED MAINTENANCE
CB3E2q (q = ±1): a family of “hyparene” analogues with a planar pentacoordinate carbon†
Abstract
A CB3 moiety extracted from the building units of milestone “hyparenes” (families of species with a planar pentacoordinate carbon (ppC)) was found to be a more basic building block, which can be employed to design a family of “hyparene” analogues CB3E2q (q = ±1) also with a ppC. The majority of main group elements can feasibly serve as the E atom. Despite the number of valence electrons, the ppC atoms in the CB3E2q (q = ±1) species were involved in three delocalized σ orbitals and a delocalized π orbital, so the carbon atom obeys the octet rule. The NICS studies indicated that these ppC structures are σ and π double aromatic. Given that most of them are less favourable in energy than their boron-centered isomers, it is remarkable that the global minimum of CB3Mg2− adopts the ppC arrangement. Such a ppC structure is also kinetically stable. Compared to previously reported anionic ppC global minima, CB3Mg2− does not contain hyper toxic beryllium and thus is much more attractive to our experimental colleagues for realizing the ppC species using negative ion photoelectron detachment spectroscopy.
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