Issue 18, 2018

Multinuclear solid-state NMR study: a powerful tool for understanding the structure of ZnO hybrid nanoparticles

Abstract

Characterization of hybrid materials is crucial for gaining an in-depth understanding of nano-objects. Here, it is evidenced that the use of multinuclear 1H, 2H, 13C, 15N, 67Zn and 17O MAS NMR spectroscopy is a very powerful approach to acquire both structural and dynamic information on hybrid ZnO nanomaterials prepared from an organometallic approach. Not only is the coordination mode of the organic part onto the inorganic surface evidenced but also important information about the dynamics of the organic capping molecules and some particularities of the nanocrystal structure itself are obtained.

Graphical abstract: Multinuclear solid-state NMR study: a powerful tool for understanding the structure of ZnO hybrid nanoparticles

Supplementary files

Article information

Article type
Paper
Submitted
16 Feb 2018
Accepted
05 Apr 2018
First published
05 Apr 2018

Phys. Chem. Chem. Phys., 2018,20, 12413-12421

Multinuclear solid-state NMR study: a powerful tool for understanding the structure of ZnO hybrid nanoparticles

G. Spataro, Y. Champouret, P. Florian, Y. Coppel and M. L. Kahn, Phys. Chem. Chem. Phys., 2018, 20, 12413 DOI: 10.1039/C8CP01096J

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