Fluorescent chirality recognition by simple boronate ensembles with aggregation-induced emission capability

Meiko Kawai; Ayaka Hoshi; Ryuhei Nishiyabu; Yuji Kubo

doi:10.1039/C7CC05784A

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Fluorescent chirality recognition by simple boronate ensembles with aggregation-induced emission capability†

Meiko Kawai,^a Ayaka Hoshi,^a Ryuhei Nishiyabu

^a and Yuji Kubo

*^a

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* Corresponding authors

^a Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-ohsawa, Hachioji, Tokyo 192-0397, Japan
E-mail: yujik@tmu.ac.jp
Fax: +81 42-677-3134
Tel: +81 42-677-3134

Abstract

Chiral ensembles were spontaneously formed in solution through boronate esterification of structurally defined di(boronic acid)-appended tetraphenylethylene (DB-TPE) and commercially available L- or D-tartaric acid, showing enantioselective aggregation behavior for chiral diamines as well as cinchona alkaloids enabling the fluorescent recognition of their chirality.

This article is part of the themed collection: Chemosensors and Molecular Logic

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Article information

DOI: https://doi.org/10.1039/C7CC05784A
Article type: Communication
Submitted: 25 Jul 2017
Accepted: 22 Aug 2017
First published: 22 Aug 2017

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Chem. Commun., 2017,53, 10144-10147

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Fluorescent chirality recognition by simple boronate ensembles with aggregation-induced emission capability

M. Kawai, A. Hoshi, R. Nishiyabu and Y. Kubo, Chem. Commun., 2017, 53, 10144 DOI: 10.1039/C7CC05784A

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Chemical Communications

Fluorescent chirality recognition by simple boronate ensembles with aggregation-induced emission capability†

Abstract

Supplementary files

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Fluorescent chirality recognition by simple boronate ensembles with aggregation-induced emission capability

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