Issue 82, 2016, Issue in Progress
From the journal:

RSC Advances

Palladium-catalyzed carbonylation of aryl halides: an efficient, heterogeneous and phosphine-free catalytic system for aminocarbonylation and alkoxycarbonylation employing Mo(CO)6 as a solid carbon monoxide source†

Abdol-Reza Hajipour,*ab   Zeinab Tavangar-Rizia  and  Nasser Iranpoorc  

* Corresponding authors

a Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Islamic Republic of Iran
E-mail: haji@cc.iut.ac.ir
Fax: +98 311 391 2350
Tel: +98 311 391 3262

b Department of Neuroscience, University of Wisconsin, Medical School, 1300 University Avenue, Madison, 53706-1532 WI, USA

c Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, Iran

Abstract

Immobilized palladium metal-containing magnetic nanoparticles (ImmPd(0)-MNPs) were synthesized and characterized as an immobilized, phosphine-free catalyst for carbonylation reactions, namely the alkoxycarbonylation and aminocarbonylation reactions. Various substituted aryl iodides tolerated the reaction conditions and a wide variety of alcohols and amines were used efficiently. The effects of the solvent, base, and temperature were studied in both the mentioned reactions. The developed catalytic system avoids the use of phosphine ligands and can be reused for up to eight consecutive cycles. The recycled catalyst was characterized by TEM and ICP analysis.

Graphical abstract: Palladium-catalyzed carbonylation of aryl halides: an efficient, heterogeneous and phosphine-free catalytic system for aminocarbonylation and alkoxycarbonylation employing Mo(CO)6 as a solid carbon monoxide source

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6RA18679C
Article type
Paper
Submitted
22 Jul 2016
Accepted
04 Aug 2016
First published
04 Aug 2016

RSC Adv., 2016,6, 78468-78476

Permissions

Request permissions

Palladium-catalyzed carbonylation of aryl halides: an efficient, heterogeneous and phosphine-free catalytic system for aminocarbonylation and alkoxycarbonylation employing Mo(CO)6 as a solid carbon monoxide source

A. Hajipour, Z. Tavangar-Rizi and N. Iranpoor, RSC Adv., 2016, 6, 78468 DOI: 10.1039/C6RA18679C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements