Issue 39, 2016
From the journal:

Chemical Communications

Supramolecular organic network assembled from quadruple hydrogen-bonding motifs†

Xue Huang,ab   Yan-Chao Zhaoab  and  Bao-Hang Han*a  

* Corresponding authors

a CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
E-mail: hanbh@nanoctr.cn
Tel: +86 10 8254 5576

b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

We prepared a rigid triptycene derivative with three 2-ureido-4[1H]-pyrimidinone terminals, which was employed to construct a hydrogen-bonded organic polymer (HOP-1). The supramolecular organic polymer HOP-1 was permanently porous and exhibited outstanding sorption selectivity towards carbon dioxide over nitrogen (96 at 273 K).

Graphical abstract: Supramolecular organic network assembled from quadruple hydrogen-bonding motifs

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Article information

DOI
https://doi.org/10.1039/C6CC02206E
Article type
Communication
Submitted
13 Mar 2016
Accepted
11 Apr 2016
First published
12 Apr 2016

Chem. Commun., 2016,52, 6597-6600

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Supramolecular organic network assembled from quadruple hydrogen-bonding motifs

X. Huang, Y. Zhao and B. Han, Chem. Commun., 2016, 52, 6597 DOI: 10.1039/C6CC02206E

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