Issue 10, 2016

Enhancing the plasmonic circular dichroism by entrapping chiral molecules at the core–shell interface of rod-shaped Au@Ag nanocrystals

Abstract

We report the enhancement of plasmonic circular dichroism (PCD) in cysteine-modified Au nanorods via Ag coating. The entrapment of cysteine at the Au–Ag interface effectively amplifies the local electromagnetic field and leads to strong enhancement of the PCD response. Ag coating on spherical nanoparticles modified with cysteine does not generate obvious PCD signals.

Graphical abstract: Enhancing the plasmonic circular dichroism by entrapping chiral molecules at the core–shell interface of rod-shaped Au@Ag nanocrystals

Supplementary files

Article information

Article type
Communication
Submitted
13 Oct 2015
Accepted
07 Dec 2015
First published
08 Dec 2015

Chem. Commun., 2016,52, 2059-2062

Author version available

Enhancing the plasmonic circular dichroism by entrapping chiral molecules at the core–shell interface of rod-shaped Au@Ag nanocrystals

S. Hou, J. Yan, Z. Hu and X. Wu, Chem. Commun., 2016, 52, 2059 DOI: 10.1039/C5CC08505E

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