Issue 87, 2015
From the journal:

Chemical Communications

Cyclometalated (boroxinato)gold(iii) complexes from arrested transmetalation†

Amberle R. Browne,a   Nihal Deligonul,a   Bryce L. Anderson,b   Matthias Zeller,c   Allen D. Hunterc  and  Thomas G. Gray*a  

* Corresponding authors

a Department of Chemistry, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106, USA
E-mail: tgray@case.edu

b Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA

c Department of Chemistry, Youngstown State University, 1 University Plaza, Youngstown, Ohio 44555, USA

Abstract

Organic boroxines are ubiquitous, but metallaboroxine analogues remain rare. A new class of (boroxinato)gold species are demonstrated here, as are observations of phosphorescence from boroxinato complexes. Four new compounds are crystallographically characterized.

Graphical abstract: Cyclometalated (boroxinato)gold(iii) complexes from arrested transmetalation

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Article information

DOI
https://doi.org/10.1039/C5CC05200A
Article type
Communication
Submitted
24 Jun 2015
Accepted
08 Sep 2015
First published
08 Sep 2015

Chem. Commun., 2015,51, 15800-15803

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Cyclometalated (boroxinato)gold(III) complexes from arrested transmetalation

A. R. Browne, N. Deligonul, B. L. Anderson, M. Zeller, A. D. Hunter and T. G. Gray, Chem. Commun., 2015, 51, 15800 DOI: 10.1039/C5CC05200A

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